https://support.steampowered.com/kb_article.php?ref=4502-TPJL-2656
this page shows what will be available go gift if bought twice
also it says the following line:
No. This special offer only applies to games or game packages listed above.
and unfortunately that list has no mention of portal 2
you will be able to purchase portal 2 as a gift to give out though no pass will be given when purchasing a pack containing it if you have it